Immersion nozzle for continuous casting of steel and method for continuous steel casting of steel using the immersion nozzle

ABSTRACT

Disclosed is a nozzle for continuous casting of clean steel, capable of preventing adhesion of Al 2 O 3 -based inclusions to a wall surface of the inner hole of the nozzle while fully achieving an effect of a swirl vane provided as a means to prevent occurrence of drift in molten steel passing through the inner hole. The swirl vane is disposed in the inner hole having the wall surface at least partly formed as a tubular-shaped refractory layer prepared by controlling a weight ratio of CaO/MgO and an apparent porosity to have a thickness of 3 to 20 mm, so as to prevent adhesion of Al 2 O 3 -based inclusions to the wall surface and the swirl vane while effectively maintaining the anti-drift effect for long hours. Further, inert gas is injected into a molten steel flow between an upper nozzle and the swirl vane to facilitate surfacing of Al 2 O 3 -based inclusions in a mold and reduce Al 2 O 3 -based inclusions in molten steel so as to achieve stable casting operation and high-quality steel with high cleanness.

TECHNICAL FIELD

The present invention relates to a casting nozzle for use with a molten steel vessel, such as ladle or tundish, in a process for continuous casting of molten steel, and more specifically to a continuous casting nozzle comprising a combination of an upper nozzle, a sliding nozzle, an intermediate nozzle, a lower nozzle and a submerged or immersion nozzle. In particular, the present invention relates to an immersion nozzle suitable for continuous casting of clean steel, and a method for continuous casting of clean steel, using the immersion nozzle.

BACKGROUND ART

In a process for continuous casting of aluminum-killed steel, when molten steel is deoxidized by the addition of aluminum, Al₂O₃-based inclusions formed in the molten steel adhere and build up onto an inner wall surface of a casting nozzle to cause a nozzle clogging phenomenon where an inner bore diameter of the nozzle is gradually reduced.

This nozzle clogging phenomenon leads directly to shortening of a usable life of the casting nozzle. Moreover, in consequence of the nozzle clogging phenomenon, molten steel flows into a mold at an uneven flow rate to cause drift in the mold, to cause a casting defect due to inclusion of mold powder and bubbles (so-called blowholes). These adverse affects obstruct the continuous casting operation and lead to deterioration in steel quality.

As measures against the nozzle clogging phenomenon, various proposals, such as the use of a material and structure intended to prevent adhesion of Al₂O₃, have been made.

As to the use of a material intended to prevent adhesion of Al₂O₃, there has been known a technique of inducing a reaction between CaO in a ZrO₂—CaO—C refractory material and Al₂O₃-based inclusions in molten steel to form a low-melting-point material, and melting a surface of the low-melting-point material in such a manner as to flow down together with the molten steel to obtain an anti-adhesion effect, as disclosed, for example, in the following Patent Publication 1. However, in cases where the cleanness of molten steel is relatively low, this technique cannot achieve a sufficient anti-adhesion effect, because a compound, such as CaO.6Al₂O₃, with a higher melting point than that of molten steel, is formed concurrently with the formation of the low-melting-point material.

As to the structure intended to prevent adhesion of Al₂O₃, the following Patent Publication 2 proposes an immersion nozzle for continuous casting. The immersion nozzle comprises a spiral swirl vane disposed in an inner hole thereof and designed to generate a swirling flow in molten steel passing through the inner hole, and a position and dimensions of the spiral swirl vane are adjusted to prevent adhesion of Al₂O₃-based inclusions to the spiral swirl vane. In this immersion nozzle, due to a swirling flow generated by the spiral swirl vane, low-density Al₂O₃-based inclusions and bubbles are apt to be concentrated in the center of molten steel flow on a downstream side relative to the spiral swirl vane. Thus, the molten steel flow adjacent to an inner wall surface is liable to stagnate in a region of the inner hole ranging from the spiral swirl vane to a position of a molten steel level (secondary meniscus) to cause a problem about increase in adhesion of Al₂O₃ to the inner wall in this region.

-   -   [Patent Publication 1] Japanese Patent Publication No. 07-34978     -   [Patent Publication 2] Japanese Patent Laid-Open Publication No.         2003-33846

DISCLOSURE OF THE INVENTION

[Problems that the Invention is to Solve]

In view of the above circumstances, it is an object of the present invention to provide an immersion nozzle for continuous casting of clean steel, capable of generating a swirling flow in molten steel to eliminate drift of molten steel in a mold, based on a spiral swirl vane disposed in an inner hole of the nozzle, and preventing adhesion of Al₂O₃-based inclusions to a wall surface of the inner hole while fully achieving the effect of the swirl vane.

It is an another object of the present invention to provide means for reducing an amount of adhesion of Al₂O₃-based inclusions to a wall surface of an inner hole of a continuous casting nozzle in contact of molten steel from a molten steel vessel, such as ladle or tundish, in a process for continuous casting of clean steel, such as aluminum-killed steel.

These and other objects, features, and advantages of the present invention will become apparent upon reading the following detailed description along with the accompanying drawings.

[Means for Solving the Problems]

In order to achieve the above objects, the present invention provides an immersion nozzle for continuous casting of steel, having an inner hole provided with a swirl vane for generating a swirling flow in molten steel passing therethrough (hereinafter referred to simply as “swirl vane”). The inner hole is defined by a wall surface (hereinafter referred to as “inner wall surface”) adapted to come into contact with the molten steel, and at least a part of the inner wall surface is formed of a refractory layer containing CaO and MgO. The refractory layer is prepared by controlling a weight ratio of each of CaO and MgO in the refractory layer, and an apparent porosity.

In the immersion nozzle of the present invention, the refractory layer constituting the inner wall surface may be formed as a tubular-shaped refractory layer which contains 65 mass % or more of MgO and CaO in a weight ratio of CaO/MgO ranging from 0.4 to 2.3, more preferably 0.6 to 1.5, with the remainder being primarily a carbonaceous material, and has an apparent porosity of 5 to 25 % and a thickness of 3 to 20 mm.

In the present invention, the chemical composition of the refractory layer is represented by a value measured after the inner wall surface is subjected to a heat treatment in a reduction atmosphere at a temperature of about 900 to 1200° C.

If a weight ratio of CaO/MgO is less than 0.4, adhesion of Al₂O₃-based inclusions is increased to cause a higher risk of the nozzle clogging phenomenon. If a weight ratio of CaO/MgO is greater than 2.3, CaO.Al₂O₃ or a low-melting-point material is formed to cause increase in wear of the refractory layer, even though no adhesion of Al₂O₃-based inclusions occurs.

When the refractory layer constituting the inner wall surface contains 65 mass % or more of MgO and CaO, with the remainder being primarily a carbonaceous material, such as graphite and resin, the carbonaceous material may be contained in the range of 35 to 1 mass % to provide an inner wall surface excellent in thermal-shock resistance. If a total amount of MgO and CaO is less than 65 mass %, a melting phenomenon of carbon into molten steel is accelerated to cause increase in wear. In order to prevent oxidization, the refractory layer may additionally contain 5 mass % or less of at least one selected from the group consisting of B₄C, SiC, Al and Si.

Each value of the above components is represented excluding a value of impurities which are inevitably mixed in raw materials.

A raw material of CaO or MgO constituting the nozzle of the present invention may include natural limestone, marble, dolomite ore, slaked lime, magnesia clinker, dolomite clinker, calcia clinker, cement clinker, and fluorine compounds containing calcium ion and/or magnesium ion.

While the refractory layer as a product is more improved in wear resistance and resistance against adhesion of Al₂O₃ as it has higher density, an apparent porosity of the refractory layer is preferably in the range of 5 to 25%, more preferably in the range of 10 to 20%. If the refractory layer has an apparent porosity of less than 5%, thermal-shock resistance is deteriorated to cause increase in thermal stress and a higher risk of cracks in a nozzle body. An immersion nozzle using a porous refractory layer with an apparent porosity of greater than 25% cannot withstand long hours of casting operation due to wear caused by abrasion.

A part or the whole of the inner wall surface adapted to come into contact with molten steel may be formed of a tubular-shaped refractory layer containing the above components and having a thickness of 3 to 20 mm, so as to eliminate the nozzle clogging phenomenon. If the refractory layer has a thickness of less than 3 mm, it is difficult to obtain a sufficient anti-clogging effect in long hours of actual casting operation. If the refractory layer has a thickness of greater than 20 mm, heat of molten steel during use is highly likely to cause cracks in the nozzle body pressed by the refractory layer having a larger expansion coefficient than that of the nozzle body.

In the immersion nozzle of the present invention, the swirl vane disposed in the inner hole may be prepared by twisting a tape-shaped refractory material at an angle of 80 to 180 degrees, preferably about 120 degree, on the basis of a horizontal plane, in such a manner as to be formed in a spiral shape.

The swirl vane may be fixed to the inner wall surface at any suitable position capable of preventing drift of molten steel at an outlet port of the nozzle.

In order to facilitate extracting a die form during forming the nozzle, the inner wall surface is preferably designed to have a slightly tapered shape in a direction from an inlet port toward the outlet port. Further, the inner wall surface may be partially formed with a tier or convex portion for supporting the swirl vane.

In the present invention, inert gas may be injected into molten steel from a gas injection port which is formed in a continuous casting nozzle including an upper nozzle associated with a molten steel vessel, at a position on an upstream side relative to the swirl vane disposed in the inner hole of the immersion nozzle, so as to provide excellent cleaning effect to molten steel based on a synergistic interaction with the anti drift effect of the swirl vane.

Specifically, according to a centrifugal force arising from the swirling flow in molten steel on the downstream side relative to the swirl vane, and a density difference between the molten steel and each of Al₂O₃-based inclusions in the molten steel and gas bubbles formed by the inert gas injected into the molten steel, the gas bubbles and the Al₂O₃-based inclusions are readily concentrated in the center of a molten steel flow. This increases a chance of contact between the gas bubbles and the Al₂O₃-based inclusions to allow the Al₂O₃-based inclusions to be more frequently trapped by the gas bubbles. Further, the bubbling effect makes it possible to facilitate surfacing of the Al₂O₃-based inclusions in a mold so as to provide enhanced cleanness in steel.

While the immersion nozzle of the present invention can achieve the anti-adhesion effect on Al₂O₃-based inclusions even if only a portion of the inner wall surface on the upstream side relative to the swirl vane is formed of the tubular-shaped refractory layer, the refractory layer may be formed to serve as the entire inner wall surface including a portion of the inner wall surface on a downstream side relative to the swirl vane. Further, the gas may be injected into molten steel flowing through the continuous casting nozzle including the upper nozzle associated with the molten steel vessel, at a position on the upstream side relative to the swirl vane.

A material of the swirl vane used in the present invention is not limited to a specific one. For example, the material of the swirl vane may include alumina-carbon based, alumina-silica-carbon based, zirconia-carbon based, magnesia-carbon based, magnesia-lime-carbon based and magnesia-lime based materials.

The immersion nozzle body may be made of a commonly-used refractory material having a primary component comprising carbon and at least one selected from the group consisting of alumina, zirconia and magnesia.

Further, a powder-line portion of the immersion nozzle may be made of a commonly-used zirconia-carbon-based material.

According to the present invention, a combination of the tubular-shaped refractory layer, the swirl vane and the inert gas injection makes it possible to effectively prevent adhesion of Al₂O₃-based inclusions while reliably maintaining an effect of eliminate drift of molten steel in a mold, so as to achieve enhanced cleanness in steel, stabilization in casting operation and enhancement and stabilization in steel quality. This largely contributes to reduction in production cost.

In addition, when the inert gas injection is combined with the tubular-shaped refractory layer and the swirl vane, an amount of inert gas to be injected can be reduced as compared with a case where the inert gas injection is implemented without being combined with the tubular-shaped refractory layer and the swirl vane. Thus, steel defects due to inert gas can be reduced to further accelerate enhancement and stabilization in steel quality and reduction in production cost.

BEST MODE FOR CARRYING OUT THE INVENTION

With reference to the accompanying drawings, an embodiment of the present invention will now be described.

FIRST EMBODIMENT

FIG. 1 is a sectional view showing an immersion nozzle 1 according to a first embodiment of the present invention. The immersion nozzle 1 comprises a swirl vane 4 disposed in an inner hole thereof, and a tubular-shaped refractory layer 3 serving as a portion of a wall surface of the inner hole on an upstream side relative to the swirl vane.

In FIG. 1, the reference numeral 2 indicates a powder-line portion for protecting corrosion due to mold powder which is a heat insulting material for molten steel in an immersion region. In a state when the immersion nozzle 1 is immersed in molten steel, the swirl vane 4 is disposed in the inner hole at an appropriate position above or on the upstream side relative to the powder-line portion 2, while comprehensively taking into account dimensions of the nozzle, such as a length between a molten-steel inlet port 5 and a molten-steel outlet port 6, and a diameter of the inner hole, so as to prevent drift of molten steel at the outlet port 6.

SECOND EMBODIMENT

FIG. 2 is a sectional view showing an immersion nozzle 1 according to a second embodiment of the present invention. This immersion nozzle 1 has an inner hole defined by a wall surface which is adapted to come into contact with molten steel passing therethrough, and entirely formed of a tubular-shaped refractory layer 3. Further, a swirl vane 4 is disposed in the inner hole on the upstream side relative to a powder-line portion 2.

THIRD EMBODIMENT

FIG. 3 is a sectional view showing an immersion nozzle 1 according to a third embodiment of the present invention. In the third embodiment, this immersion nozzle 1 is provided with a gas injection port 7 disposed adjacent to a molten-steel inlet port 5, and attached to an upper nozzle 12 fixed to a bottom of a molten steel vessel 13.

In the third embodiment, inert gas is fed from a gas feed port 8 formed in an outer wall of an upper portion of the immersion nozzle 1, and injected into molten steel from the gas injection port 7 through a slit 9 formed on the side of a back surface of a tubular-shaped refractory layer 3. The gas injection port 7 is formed of a gas-pervious refractory member, such as a porous refractory member or a refractory member having a through-hole.

While the swirl vane 4 and the tubular-shaped refractory layer 3 in each of the first to third embodiments are disposed in the inner hole of the immersion nozzle 1, they may be disposed at any other suitable position of a molten-steel flow passage of an intermediate nozzle (lower nozzle) 10, a sliding nozzle plate 11 or the upper nozzle 12 (see FIG. 3).

When the swirl vane 4 and/or the tubular-shaped refractory layer 3 are disposed in the molten-steel flow passage of the upper nozzle 12, they may be made of a porous material in their entirety, as in the gas injection port 7.

A casting test was carried out using each of the immersion nozzles illustrated in FIGS. 1 to 3. The test result is shown in the following Tables 1 to 4.

An immersion nozzle body in each sample of the immersion nozzles in FIGS. 1 to 3 was made of an alumina-silica-carbon-based refractory material consisting of 41 mass % of Al₂O₃, 28 mass % of SiO₂ and 31 mass % of C.

Extremely-low-carbon aluminum-killed steel containing 30 ppm of C, 0.03 mass % of Si, 0.7 mass % of Mn, 0.01 mass % of P, 0.01 mass % of S and 0.05 mass % of Al was used as molten steel for this casting test. In each of the immersion nozzles, a casting time was set at 250 minutes. A composition of each sample subjected to the test, a thickness of adhered Al₂O₃-based inclusions and a level of wear in the inner wall surface adjacent to the outlet port after the test, and a temperature difference ΔT causing cracks in connection with thermal shock applied to the sample, were checked.

Table 1 shows a relationship of Al₂O₃ buildup rate, evaluation of Al₂O₃ buildup level and thermal-shock temperature ΔT, using a CaO/MgO weight ratio as a parameter, in each sample of the immersion nozzles illustrated in FIGS. 1 and 2. TABLE 1 Comparative Comparative Sample Inventive Sample Sample 1 2 1 2 3 4 5 3 4 CaO + MgO total weight ratio 100 100 100 100 100 100 100 100 100 CaO/MgO weight ratio 0.3 0.4 0.6 1.0 1.5 2.4 3.0 Chemical MgO (mass %) 99.0 74.5 69.5 61.9 49.5 39.6 29.5 24.5 composition CaO (mass %) 24.5 29.5 37.1 49.5 59.4 69.5 74.5 99.0 C (mass %) 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 measurement alumina 0.23 0.1 0.03 0.001 0.001 0 −0.01 −0.2 −0.8 buildup rate (mm/min) evaluation of thick adhesion Good Good Good Good Good wear wear buildup level buildup thermal shock 500 520 550 550 600 600 680 780 850 resistance (temperature difference ΔT)* *Sample: cylindrical shape of Φ120/Φ80

As seen in Table 1, each of Inventive Samples 1 to 5 had a small adhesion of Al₂O₃-based inclusions and kept in a good state in all items. In contrast, each of Comparative Samples 1 and 2 having a CaO/MgO weight ratio of 0.3 or less had a high Al₂O₃ buildup rate. While each of Comparative Samples 3 and 4 having a CaO/MgO weight ratio of greater than 2.3 had no Al₂O₃ adhesion, they exhibited increase in wear. As to a temperature difference ΔT causing cracks due to thermal shock, each of Samples had a low value of 1000° C. or less because of a relatively low content of carbon, and there was no substantial difference therebetween. TABLE 2 Comparative Sample Inventive Sample 5 6 6 7 8 CaO + MgO total weight ratio 55.0 60.0 65.0 85.0 95.0 CaO/MgO weight ratio 1.0 1.0 1.0 1.0 1.0 Chemical MgO (mass %) 27.5 30.0 32.5 42.5 47.5 composition CaO (mass %) 27.5 30.0 32.5 42.5 47.5 C (mass %) 45.0 40.0 35.0 15.0 5.0 measurement alumina buildup rate (mm/min) −0.8 −0.3 −0.1 −0.03 −0.01 evaluation of buildup level large wear large wear Good Good Good thermal shock resistance >1500 >1500 1350 1100 1000 (temperature difference ΔT)* *Sample: cylindrical shape of Φ120/Φ80

Table 2 shows the result of a test using Samples each having a CaO/MgO weight ratio fixed at 1 and a different carbon content. As seen in Table 2, Sample having a carbon content of 5 mass % or more exhibits a temperature difference ΔT of 1000° C. or more. In particular, Inventive Samples 6 to 8 having a carbon content of 35 mass % or less or a total mass % of CaO and MgO of 65 mass % or more had neither wear nor Al₂O₃ adhesion and exhibited a well-balanced state. In contrast, each of Comparative Samples 5 and 6 having an excessively high carbon content exhibited severe wear due to reaction between carbon and molten steel during an Al₂O₃ buildup test. TABLE 3 Inventive Sample Comparative Sample 7 9 10 7 8 9 CaO + MgO total weight ratio 85.0 85.0 85.0 85.0 85.0 85.0 CaO/MgO weight ratio 1.0 1.0 1.0 1.0 1.0 1.0 Chemical MgO (mass %) 42.5 42.5 42.5 42.5 42.5 42.5 composition CaO (mass %) 42.5 42.5 42.5 42.5 42.5 42.5 C (mass %) 15.0 15.0 15.0 15.0 15.0 15.0 measurement apparent porosity (%) 5 14 25 28 35 3 alumina buildup rate (mm/min) −0.03 −0.05 −0.08 −0.15 −0.4 −0.03 evaluation of buildup level Good Good Good wear wear Good thermal shock resistance 1100 1150 1200 1300 1350 900 (temperature difference ΔT)* *Sample: cylindrical shape of Φ120/Φ80

Table 3 shows the result of an Al₂O₃ buildup test using samples prepared by using a composition of Inventive Sample 7 and changing a forming pressure from 300 to 2500 kg/cm² to have different apparent porosities after burning under a reduction atmosphere at a temperature of 1000° C. Inventive Samples 7, 9 and 10 having an apparent porosity of 25% or less had no Al₂O₃ adhesion based on a slight wear and kept in a good state. In contrast, Comparative Samples 7 and 8 having an apparent porosity of 28% or more exhibited large wear even though no Al₂O₃ adhesion was observed. Comparative Sample 9 having an apparent porosity of 3% exhibited poor thermal-shock resistance even through it had no problem in terms of wear and Al₂O₃ adhesion. TABLE 4 Comparative Inventive Sample 10 Sample 11 Nozzle Structure Amount of Argon Gas 0 3 NL/min Amount of Alumina Inclusions in Slab (Index) 100 40

The above Table 4 shows the result of a test where the immersion nozzle illustrated in FIG. 3 having the refractory layer of Inventive Sample 7 in Table 3 was used, and inert gas was injected into the molten steel from the gas injection port made of a gas-pervious refractory material and disposed on an upstream side relative to the swirl vane.

Given that an amount of Al₂O₃-based inclusions in slab cast by injecting no argon gas is 100 as shown in Comparative Sample 10, an amount of Al₂O₃-based inclusions in slab cast by injecting argon gas at 3 NL/min was reduced to 40% as shown in Inventive Sample 11.

In a casting operation using an immersion nozzle having the refractory layer of Inventive Sample 7, the immersion nozzle could stably maintained an effect of the swirl vane during the entire period of the casting operation without adhesion of Al₂O₃-based inclusions and the nozzle-clogging phenomenon, and a product could be obtained without surface and internal defects. Further, when inert gas was injected into molten steel from the gas injection port made of a gas-pervious refractory material and disposed on an upstream side relative to the swirl vane, an amount of Al₂O₃-based inclusions was drastically reduced, and a high-quality product free of surface and internal defects could been obtained.

In contrast, when only the swirl vane was used without using the refractory layer, Al₂O₃-based inclusions built up onto the swirl vane and the inner wall surface on the upstream side of the swirl vane in the form of a layer having a thickness of 7 to 8 mm to obstruct a stable casting operation.

INDUSTRIAL APPLICABILITY

According to the present invention, in a process for continuous casting of molten steel, using a casting nozzle comprising a combination of an upper nozzle, a sliding nozzle, a nozzle, a lower or intermediate nozzle and an immersion nozzle, associated with a molten steel vessel, such as ladle or tundish, the tubular-shaped refractory layer formed in each of the nozzles to serve as at least a part of an inner wall surface thereof adapted to come into contact with molten steel can prevent occurrence of a nozzle clogging phenomenon, and a portion of the refractory layer formed on an upstream side of the swirl vane disposed in an inner hole of the immersion nozzle can prevent adhesion of Al₂O₃-based inclusions to the swirl vane due to stagnation of a molten steel flow in the inner hole around a molten steel level (secondary meniscus). Based on synergistic effects with bubbling, the present invention is suitably used in continuous casting of clean steel.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a sectional view showing an immersion nozzle according to one embodiment of the present invention, wherein the immersion nozzle comprises a swirl vane disposed in an inner hole thereof, and a tubular-shaped refractory layer serving as a portion of a wall surface of the inner hole on an upstream side relative to the swirl vane.

FIG. 2 is a sectional view showing an immersion nozzle according to another embodiment of the present invention, wherein the immersion nozzle comprises a tubular-shaped refractory layer serving as the entire wall surface of an inner hole thereof, and a swirl vane disposed in the inner hole.

FIG. 3 is a sectional view showing an immersion nozzle according to yet another embodiment of the present invention, wherein the immersion nozzle comprises a swirl vane disposed in an inner hole thereof, a tubular-shaped refractory layer serving as a portion of a wall surface of the inner hole on an upstream side of the swirl vane, and an inert-gas injection port disposed on the upstream side relative to the swirl vane.

DESCRIPTION OF THE REFERENCE NUMERALS AND SIGNS

-   1: immersion nozzle -   2: powder-line portion -   3: tubular-shaped refractory layer -   4: swirl vane -   5: molten-steel inlet port -   6: molten-steel outlet port -   7: gas injection port -   8: gas feed port -   9: slit -   10: intermediate nozzle (lower nozzle) -   11: sliding nozzle plate -   12: upper nozzle -   13: molten steel vessel 

1.-13. (canceled)
 14. An immersion nozzle for continuous casting of steel, having an inner hole provided with a swirl vane for generating a swirling flow in molten steel passing therethrough, said inner hole having a wall surface adapted to come into contact with the molten steel during use, at least a part of wall surface being formed of a refractory layer containing CaO and MgO, said refractory layer being prepared by controlling a weight ratio of each of CaO and MgO in said refractory layer, and an apparent porosity.
 15. The immersion nozzle as defined in claim 14, wherein said CaO—MgO-containing refractory layer contains a carbonaceous material, wherein a sum of respective chemical composition of MgO and CaO in said refractory layer is 65 mass % or more, and a weight ratio of CaO/MgO is in the range of 0.4 to 2.3.
 16. The immersion nozzle as defined in claim 15, wherein said CaO—MgO-containing refractory layer is formed as a tubular-shaped refractory layer having an apparent porosity of 5 to 25% and a thickness of 3 to 20 mm.
 17. The immersion nozzle as defined in claim 15, wherein said carbonaceous material is contained in said CaO—MgO-containing refractory layer in the range of 1 to 35 mass %.
 18. The immersion nozzle as defined in claim 15, wherein said CaO—MgO-containing refractory layer contains 5 mass % or less of at least one selected from the group consisting of B₄C, SiC, Al and Si.
 19. The immersion nozzle as defined in claim 14, wherein said swirl vane is prepared by twisting a tape-shaped refractory material at an angle of 80 to 180 degrees on the basis of a horizontal plane, in such a manner as to be formed in a spiral shape.
 20. The immersion nozzle as defined in claim 14, wherein the wall surface of said inner hole is partially formed with a tier or convex portion, and said swirl vane is fixed to said tier or convex portion.
 21. The immersion nozzle as defined in claim 14, which has a gas injection port located on an upstream side relative to said swirl vane.
 22. The immersion nozzle as defined in claim 14, wherein said CaO—MgO-containing refractory layer is formed to serve as the entire wall surface of said inner hole including a portion of said wall surface on a downstream side relative to said swirl vane.
 23. The immersion nozzle as defined in claim 1, wherein said swirl vane is disposed in said inner hole on an upstream side relative to a position corresponding to a powder line.
 24. The immersion nozzle as defined in claim 21, wherein said CaO—MgO-containing refractory layer is formed as a lubular-shaped refractory layer, wherein said immersion nozzle is designed such that gas inert relative to steel is supplied into molten steel passing through said inner hole, from a gas injection port disposed on an upstream side relative to said swirl vane, through a space formed on the side of a back surface of said tubular-shaped refractory layer from a gas feed port formed in the immersion nozzle.
 25. A method for continuous casting of steel, using a continuous casting nozzle having an inner hole which is provided with a swirl vane for generating a swirling flow in molten steel passing therethrough, and defined by a wall surface adapted to come into contact with the molten steel during use, at least a part of said wall surface being formed of a tubular-shaped refractory layer, wherein: said steel is clean steel; and said refractory layer contains a carbonaceous material, MgO and CaO, wherein a total amount of MgO and CaO is 65 mass % or more, and a weight ratio of CaO/MgO is in the range of 0.4 to 2.3, said refractory layer having an apparent porosity of 5 to 25%.
 26. The method as defined in claim 25, which including injecting inert gas into molten steel passing through said inner hole, from a gas injection port which is formed in said continuous casting nozzle including an upper nozzle associated with a molten steel vessel, at a position on an upstream side relative to said swirl vane. 